Steve ,a simple compression test of all cylinders will tell you where your at regarding performance and general condition..........make sure you correctly adjust the shim/valve clearance before you do this.
A way to measure wear on both the barrels and rings at the same time........is to measure the gap where the ring meets.... whilst the piston and rings are still in the bore.
A visual inspection internally of the barrels will show any scratches /damage.............
Usually a hone of the cylinders and new rings with a clean up of the pistons......decoke.......will suffice.
What is the reason you wish to check the barrels.